The effect of the lateral interactions on the critical behavior of long straight rigid rods on two-dimensional lattices

Using Monte Carlo simulations and finite-size scaling analysis, the critical behavior of attractive rigid rods of length k (k-mers) on square lattices at intermediate density has been studied. A nematic phase, characterized by a big domain of parallel k-mers, was found. This ordered phase is separated from the isotropic state by a continuous transition occurring at a intermediate density \theta_c, which increases linearly with the magnitude of the lateral interactions.Comment: 7 pages, 6 figure

Critical behavior of long straight rigid rods on two-dimensional lattices: Theory and Monte Carlo simulations

The critical behavior of long straight rigid rods of length $k$ ($k$-mers) on square and triangular lattices at intermediate density has been studied. A nematic phase, characterized by a big domain of parallel $k$-mers, was found. This ordered phase is separated from the isotropic state by a continuous transition occurring at a intermediate density $\theta_c$. Two analytical techniques were combined with Monte Carlo simulations to predict the dependence of $\theta_c$ on $k$, being $\theta_c(k) \propto k^{-1}$. The first involves simple geometrical arguments, while the second is based on entropy considerations. Our analysis allowed us also to determine the minimum value of $k$ ($k_{min}=7$), which allows the formation of a nematic phase on a triangular lattice.Comment: 23 pages, 5 figures, to appear in The Journal of Chemical Physic

Experimental violation of a spin-1 Bell inequality using maximally-entangled four-photon states

We demonstrate the first experimental violation of a spin-1 Bell inequality. The spin-1 inequality is a calculation based on the Clauser, Horne, Shimony and Holt formalism. For entangled spin-1 particles the maximum quantum mechanical prediction is 2.552 as opposed to a maximum of 2, predicted using local hidden variables. We obtained an experimental value of 2.27 $\pm 0.02$ using the four-photon state generated by pulsed, type-II, stimulated parametric down-conversion. This is a violation of the spin-1 Bell inequality by more than 13 standard deviations.Comment: 5 pages, 3 figures, Revtex4. Problem with figures resolve

Critical behavior of self-assembled rigid rods on triangular and honeycomb lattices

Using Monte Carlo simulations and finite-size scaling analysis, the critical behavior of self-assembled rigid rods on triangular and honeycomb lattices at intermediate density has been studied. The system is composed of monomers with two attractive (sticky) poles that, by decreasing temperature or increasing density, polymerize reversibly into chains with three allowed directions and, at the same time, undergo a continuous isotropic-nematic (IN) transition. The determination of the critical exponents, along with the behavior of Binder cumulants, indicate that the IN transition belongs to the q=1 Potts universality class.Comment: 6 pages, 5 figure

Entropy-driven phase transition in a system of long rods on a square lattice

The isotropic-nematic (I-N) phase transition in a system of long straight rigid rods of length k on square lattices is studied by combining Monte Carlo simulations and theoretical analysis. The process is analyzed by comparing the configurational entropy of the system with the corresponding to a fully aligned system, whose calculation reduces to the 1D case. The results obtained (1) allow to estimate the minimum value of k which leads to the formation of a nematic phase and provide an interesting interpretation of this critical value; (2) provide numerical evidence on the existence of a second phase transition (from a nematic to a non-nematic state) occurring at density close to 1 and (3) allow to test the predictions of the main theoretical models developed to treat the polymers adsorption problem.Comment: 14 pages, 6 figures. Accepted for publication in JSTA